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Major phytocannabinoid

Unscheduled

CBCACannabichromenic acid

5-hydroxy-2-methyl-2-(4-methylpent-3-enyl)-7-pentylchromene-6-carboxylic acid

Aliases.acide cannabichroménique · CBC-A · Cannabichromenic acid

The acid, unheated form of cannabichromene (CBC).

Updated on

Level of detail

Harm-reduction warning

No characterised human dose: animal / in vitro data only. Effect profile, safety margin and acute toxicity are not documented in human clinical practice. Extremely potent compound: severe effects, seizures and deaths reported in the literature.

Identifiers

Formula
C₂₂H₃₀O₄
Molar mass
358.50 g·mol⁻¹
CAS
20408-52-0
PubChem CID
3084339
First described
1968
Origin
Hemp (Cannabis sativa L.): a natural acidic cannabinoid present in the fresh plant
InChIKey
HRHJHXJQMNWQTF-UHFFFAOYSA-N

In plain terms

CBCA is the acid, natural form of CBC, as found in the hemp plant before any heating.

Receptors and activity

  • CB1
    Modulator
  • CB2
    Modulator
  • Agonist
  • Partial agonist
  • Antagonist
  • Modulator
  • Inverse agonist

Hover over a row for the precise value (Ki, EC50…)

Subjective signature

Hover over an axis to read its definition.

  • Calm
    25
  • Clarity
    15
  • Sleep
    15
  • Appetite
    20
  • High
    10

Editorial estimate, not clinical.

Pharmacology

CBCA (cannabichromenic acid) is a minor acidic cannabinoid, the direct precursor of cannabichromene (CBC). It is synthesised in the plant from cannabigerolic acid (CBGA) under the action of CBCA synthase, which closes the side chain into a chromene ring (source: PubChem; Wikipedia). Non-intoxicating, it converts into CBC by decarboxylation under the effect of heat. Its own properties remain little characterised: the available data concern chiefly its decarboxylated derivative, CBC, which notably modulates the CB2 receptor and the TRPA1 channel.

Biosynthetic pathway

CBCA is produced in the hemp plant from cannabigerolic acid (CBGA), the common precursor of the cannabinoids. The enzyme CBCA synthase catalyses the oxidative cyclisation of the monoterpene chain of CBGA (or of its isomer, cannabinerolic acid) to form the characteristic chromene nucleus. Subsequent decarboxylation, brought about by heat or ageing, converts CBCA into cannabichromene (CBC).

Structural classification

Class
Major phytocannabinoid
Origin
Hemp (Cannabis sativa L.): a natural acidic cannabinoid present in the fresh plant
Status
Unscheduled

Acide cannabinoïde de type chromène (chromén-6-carboxylique), portant une fonction phénol, une chaîne pentyle et un groupe carboxyle libre : la forme acide du cannabichromène.

Detection and analysis

En chromatographie liquide (HPLC), qui n'échauffe pas l'échantillon, le CBCA est dosé tel quel comme marqueur des cannabinoïdes acides d'une plante non chauffée ; en chromatographie gazeuse (GC), la chaleur le décarboxyle et il est alors mesuré sous la forme de CBC.

References

  1. 1.PubChem CID 3084339 : Cannabichromenic acid (formule, masse, InChIKey, IUPAC, synonymes, CAS)
  2. 2.Cannabichromenic acid : Wikipedia (précurseur du CBC, biosynthèse via CBCA synthase, première description 1968)

Structured data

InChIKey
HRHJHXJQMNWQTF-UHFFFAOYSA-N
SMILES
CCCCCC1=CC2=C(C=CC(O2)(C)CCC=C(C)C)C(=C1C(=O)O)O
Formula
C22H30O4
Molar mass
358.50 g·mol⁻¹
CAS
20408-52-0
PubChem CID
3084339
Machine-readable entry (JSON)

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